A Chemoenzymatic Synthesis of the Sex Pheromone of Lasioderma

نویسندگان

  • Ronaldo A. Pilli
  • Valéria B. Riatto
چکیده

A síntese quimioenzimática da forma enantiomericamente enriquecida (80% ee) da (-)-serricornina (1), feromônio sexual da praga do fumo Lasioderma serricorne F., foi alcançada em 8 etapas e 13% de rendimento total a partir de (R)-3-hidroxipentanoato de metila, obtido da redução de 3-oxopentanoato de metila com fermento de padaria (S. cerevisiae) na presença de álcool alílico como inibidor enzimático.

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تاریخ انتشار 1999